王伟和吴金泽同学在ACS期刊Macromolecules上发表最新文章《Annealing To Induce Formation of Defects in Polyether/Li+ Complex Crystals – A Way To Significantly Enhance the Crystalline Segmental Mobility》。
(https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.9b01086，Publication Date:July 31, 2019，https://doi.org/10.1021/acs.macromol.9b01086)。
In this work, we demonstrate that a deliberately designed annealing process can induce formation of defects in polyether/Li+ complex crystals. The Li+ concentration diffusion in the complex crystals and the amorphous structures is considered to play a critical role in the formation of crystal defects. The 13C 2D exchange NMR shows that the annealing-induced crystal defects can greatly enhance the segmental mobility in the polyether/Li+ complex crystals. The rate of helical jump motions in the deliberately annealed polyether/Li+ complex crystals is ∼100 times higher than those reported in the literature. This work deepens our understanding of the defect formation in polyether/Li+ complex crystals and has important implications on the ionic conduction enhancement of polyether-based crystalline polymer electrolytes.
